Decomposition is not an obligatory step in wavefront analysis. First look at the shape across the pupil in the wavefront map and get the size from the PV and RMS values. Move on to Zernike polynomials when you want to treat which aberration contributes how much as an allocation. OpticStudio has three sets. The standard set is an orthonormal system based on Noll’s notation, in which the magnitude of each coefficient corresponds directly to that term’s RMS contribution, and up to 231 terms are supported. The fringe set is not orthonormal, is normalized to unit magnitude at the pupil edge, and has up to 37 terms. The annular set adds Mahajan’s extension to annular pupils to Noll’s notation and is used with an obscuration ratio specified. At an obscuration ratio of 0, the annular set coincides with the standard set.
The premise of the decomposition is that the rays are uniformly arranged on normalized pupil coordinates. If the rays are not uniformly sampled at the surface being evaluated, the result is not correct. For a rotationally symmetric system made only of spherical, conic, and second- or fourth-order aspheric surfaces, the classical breakdown of aberrations can be confirmed through Seidel coefficients. That calculation is valid only for systems meeting those conditions. It cannot be used for systems with coordinate breaks, diffraction gratings or non-rotationally-symmetric surfaces.